A bi-TTF with a bipyridine spacer: 4,4′-bis[(3,6,7-trimethylsulfanyltetrathiafulvalen-2-yl)sulfanylmethyl]-2,2′-bipyridine
A bi-TTF with a bipyridine spacer: 4,4′-bis[(3,6,7-trimethylsulfanyltetrathiafulvalen-2-yl)sulfanylmethyl]-2,2′-bipyridine
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The title compound, C30H28N2S16, is a precursor to hybrid magnetic materials.The complete molecule is generated by a teeter totter cabernet 2019 crystallographic inversion centre.In the crystal structure, the TTF core is not planar and adopts a chair conformation; the soderhamn ottoman cover two C3S2 rings are folded around the S.S hinges, the dihedral angles being 17.14 (8) and 13.
46 (7)°.There is a short S.S contact [3.4863 (14) Å] in the crystal structure.